Synthesis of MgMnSiO4 and Its Application as Cathode Material for Magnesium Battery

Synthesis of MgMnSiO4 and Its Application as Cathode Material for Magnesium Battery

Jianzhi Sun*
Zhen Jiang

College of Chemistry and Chemical Engineering, Dezhou University, Shandong Dezhou , P. R. China; 253023

Corresponding Author Email: 
jianzhisun@163.com
Page: 
009-011
|
DOI: 
https://doi.org/10.14447/jnmes.v17i1.436
Received: 
November 24, 2013
| |
Accepted: 
December 16, 2013
| | Citation
Abstract: 

Orthosilicate MgMnSiO4 was prepared by sol-gel route and a subsequent heating procedure as a cathode material for rechargeable magnesium batteries. XRD patterns showed that MgMnSiO4 has a orthorhombic system with space group Pbnm(62). MgMnSiO4 presents good electrochemical behaviors at 10 mAg-1 discharge current density with specific capacity 130.1 mAhg-1 after 20 cycles. The results show that MgMnSiO4 could be a potential cathode material for high-energy magnesium secondary battery.

Keywords: 

Magnesium battery; MgMnSiO4; positive electrode

1. Introduction
2. Experimiental
3. Results and Discussion
4. Conclusion
5. Acknowledgments

This work was supported by a grant from the Natural Science Foundation of Shandong (No. ZR2009FQ027) and the National Undergraduate Training Programs for Innovation and Entrepreneurship (201310448025).

  References

[1] J. Giraudet, D. Claves, K. Guérin, M. Dubois, A. Houdayer, F. Masin, A. Hamwia, J. Power Sources, 173, 592 (2007).

[2] R. Shahid, S. Shinya, Y. Shu, M. Masaru, Solid State Ionics, 225, 542 (2012).

[3] T. Kakibe, J. Hishii, N. Yoshimoto, M. Egashira, M. Morita, J. Power Sources, 203, 195 (2012).

[4] J.Z. Sun, J. New Mat. Electrochem. Systems, 16, 253 (2013).

[5] Aurbach D., Z. Lu, A. Schechter, Nature, 407, 724 (2000).

[6] N. Amir, Y. Vestfrid, O. Chusid, Y. Gofer, D. Aurbach, J. Power Sources, 174, 1234 (2007).

[7] T. Kakibe, N. Yoshimoto, M. Egashira, M. Morita, Electrochem. Commun., 12, 1630 (2010).

[8] Y.S. Guo, J. Yang, Y.N. Nuli, J.L. Wang, Electrochem. Commun., 12, 1671 (2010).

[9] Y.N. Nuli, Y.P. Zheng, F. Wang, J. Yang, A.I. Minett, J.L. Wang, J. Chen. Electrochem. Commun., 13, 1143 (2011).

[10] R. Rinaldi, G.D. Gatta, G. Artioli, K.S. Knight, C.A. Geiger, Phys. Chem. Miner., 32, 655 (2005).