Long-Term Performance of Contacting Concrete and Smectite Clay in Deep Disposal of Highly Radioactive Waste

Long-Term Performance of Contacting Concrete and Smectite Clay in Deep Disposal of Highly Radioactive Waste

R. Pusch T. Yang 

Dept. of Civil, Environmental and Natural resources Eng., Luleå University of Technology, Luleå, Sweden

Page: 
740-750
|
DOI: 
https://doi.org/10.2495/SDP-V11-N5-740-750
Received: 
N/A
| |
Accepted: 
N/A
| | Citation

OPEN ACCESS

Abstract: 

Disposal of highly radioactive waste (HLW) can be environmentally acceptable if radionuclides are kept isolated from the groundwater, which has inspired planners of repositories to work out multibarrier concepts that postulate defined functions of the host rock and engineering barriers. Assessment of the role of the host rock involves groundwater flow modelling and rock mechanical analysis, which are both highly speculative and ignore future changes in rock structure, stress conditions, and groundwater flow. This makes use of engineered barriers necessary and possible technical solutions for isolating containers with HLW by clay and concrete seals have been described in the literature. The present paper examines the performance and interaction of such seals in very deep boreholes with respect to chemical reactions and their impact on the sealing functions.

Keywords: 

cation exchange, clay, concrete, dissolution of clay minerals, interaction of smectite and cement

  References

[1] Pusch, R., Ramqvist, G. & Knutsson, S., Modern techniques for sealing deep cored boreholes. Engineering Geology, 202, pp. 132–142, 2016. http://dx.doi.org/10.1016/j.proeps.2015.08.038

[2] Pusch, R., A technique to delay hydration and maturation of borehole seals of expansive clay. Engineering Geology, 121, pp. 1–6, 2011. http://dx.doi.org/10.1016/j.enggeo.2011.04.017

[3] Yang, T., Pusch, R., Knutsson, S., Liu, X., Lab testing of method for clay isolation of spent reactor fuel in very deep boreholes. In Proceeding World Multidisciplinary Earth Sciences Symposium - WMESS 2015, September 7–11, Prague, Czech Republic, 2015. http://dx.doi.org/10.1016/j.proeps.2015.08.038

[4] Warr, L.N. & Grathoff, G.H., Sealing of investigation boreholes: Mineralogical and geochemical borehole plug analyses. Technical report, swedish nuclear fuel and waste management co., Ernst-Moritz-Arndt-Universität, Greifswald, Germany, 2010.

[5] Pusch, R., Warr, L., Grathoff, G., Pourbakhtiar, A., Knutsson, S. & Mohammed M.H., A talc-based cement-poor concrete for sealing boreholes in rock. Engineering Geology, 5, pp. 251–267, 2013. http://dx.doi.org/10.4236/eng.2013.53036

[6] Pusch, R., Chemical interaction of clay Buffer Materials and concrete. Swedish Nuclear Fuel and Waste Management Co (SKB). Report SFR 82-01, 1982.

[7] Pusch, R., Zwahr, H., Gerber, R. & Schomburg, J., Interaction of cement and smectite clay – theory and practice. Applied Clay Science, 23, pp. 203–210, 2003. http://dx.doi.org/10.1016/S0169-1317(03)00104-2 

[8] Pusch, R., Geological Storage of Radioactive Waste, Springer-Verlag, Berlin, Heidelberg, ISBN: 978-3-540-77332-0, 2008 http://dx.doi.org/10.1007/978-3-540-77333-7

[9] Lindgreen, H., Elemental and structural changes in illite/smectite mixed-layer clay minerals during diagenesis in Kimmeridgian- Volgian (- Ryazanian) clays in the Central Trough, North Sea and the Norwegian-Danish Basin. Bull. Geol. Soc. Denmark, 39, pp. 1–82, 1991.

[10] Gueven, N. & Huang, W-L., Effects of Mg2+ and Fe3+ substitutions on the crystallization of discrete illite and illite/smectite mixed layers. Dept. Geosciences Texas Tech University, Exxon Production research Co, Houston, Texas, USA, 1990.

[11] Pusch, R., Yong, R.N. & Nakano, M., Stiffening of smectite buffer clay by hydrothermal effects. Engineering Geology, 110, pp. 21–31, 2010. http://dx.doi.org/10.1016/j.enggeo.2010.07.002

[12] Pusch, R., Bentonite Clay, CRC Press (Taylor & Francis Group), ISBN 13:978-1-4822-4343-7, 2015.

[13] Mohammed, M.H., Pusch, R., Al-Ansari, N., Knutsson, S., Emborg, M., Nilsson, M. & Pourbakhtiar, A., Talc-based concrete for sealing borehole optimized by using particle packing theory. Journal of Civil Engineering and Architecture, 7(4), pp. 440–455, 2013.