Treatment of Short-chain Nonylphenol Polyethoxylates by the Technique of Combing Biological Contact Oxidation with an Anoxic/oxic Membrane Bioreactor

Treatment of Short-chain Nonylphenol Polyethoxylates by the Technique of Combing Biological Contact Oxidation with an Anoxic/oxic Membrane Bioreactor

Jia Ruotan Wang Jie  Xiang Yang  Fan Shiliang  Li Liangchao  Li Xianjing  Wang Min  Xie Yuanhua  Zhu Tong 

School of Mechanical Engineering and Automation, Northeastern University, Shenyang 110004, Liaoning, China

Liaoning Province Petroleum-chemical Industry Planning & Designing Institute Co, Ltd, Shenyang 110000, Liaoning, China

Corresponding Author Email: 
tongzhu@mail.neu.edu.cn
Page: 
23-26
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DOI: 
10.18280/eesrj.030201
Received: 
| |
Accepted: 
| | Citation

OPEN ACCESS

Abstract: 

The technique of combing biological contact oxidation with an anoxic/oxic membrane bioreactor was designed for the treatment of short-chain nonylphenol polyethoxylates (SC-NPnEO, n<3). The temperature (T), dissolved oxygen (DO) and hydraulic retention time (HRT) were selected as influence factors by an orthogonal experiment of three factors and three levels. Degradation effect of NPEO 0~5 and other components were selected as the evaluation index for the orthogonal experiment, evaluating the influence degree of each parameter to the degradation of the target pollutant, and determining the optimum condition of the system operation. The results showed that the removal rate of COD and NH4+-N was stable at more than 85%, and the average removal rate of NPEO0~5 was remained above 98%. The optimum operation parameters of the system were achieved as temperature of 33℃, DO of 5mg/L, HRT of 24h. The largest influence factor to the degradation of total NPEO0~5 was DO, followed by temperature and HRT. These results showed the technique of combing biological contact oxidation with an anoxic/oxic membrane bioreactor had good sludge retention capacity and shock load resistance capacity and efficient degradation of SC-NPnEO and water pollutants, has broad application prospects.

Keywords: 

Anoxic/oxic, Biological degradation, Contact oxidation, Membrane bioreactor, Short-chain nonylphenol polyethoxylates

1. Introduction
2. Experimental Section
3. Results and Discussion
4. Conclusions
Acknowledgement
  References

[1] Lu J., Jin Q., He Y., et al, “Biodegradation of nonylphenol polyethoxylates under sulfate-reducing conditions,” Science of the Total Environment, vol. 399, no. 1-3, pp. 121–127, 2008. DOI: 10.1016/j.scitotenv.2008.01.003.

[2] Okayasu Y, Komori K, Suzuki Y, et al, “Nonylphenol formation from nonylphenol ethoxylates in activated sludge process,” Journal of Japan Society on Water Environment, vol. 28, no. 11, pp. 671–676, 2005. DOI: 10.2965/jswe.28.671.

[3] Różalska S, Szewczyk R, Długoński J, “Biodegradation of 4- n -nonylphenol by the non-ligninolytic filamentous fungus Gliocephalotrichum simplex: A proposal of a metabolic pathway,” Journal of Hazardous Materials, vol. 180, no.1-3, pp.323–331, 2010. DOI: 10.1016/j.jhazmat.2010.04.034.

[4] X.J. Ma, B. Shao, J.Y. Hu et al, “Transformation behavior of nonylphenol migration in the sewage treatment process,” Environmental Science, vol. 23, no. 5, pp. 80–83, 2002. DOI: 10.1016/j.biortech.2014.05.119.

[5] Okayasu Y, Komori K, Suzuki Y, Tanaka H, Yasojima M, “Nonylphenol formation from nonylphenol ethoxylates in activated sludge process,” Journal of Japan Society on Water Environment, vol. 28, no. 11, pp. 671–676,  2005. DOI: 10.2965/jswe.28.671.

[6] Chang B V, Chiang F, Yuan S Y, “Biodegradation of nonylphenol in sewage sludge,” Chemosphere, vol. 60,  pp. 1652–1659,  2005. DOI: 10.1016/j.chemosphere.2005.02.042.

[7] Hernandez-Raquet G, Soef A, Delgenès N, et al, “Removal of the endocrine disrupter nonylphenol and its estrogenic activity in sludge treatment processes,” Water Research, vol. 41, no. 12, pp. 2643–2651, 2007. DOI: 10.1016/j.watres.2007.02.039.

[8] Yuan S Y, Yu C H, Chang B V, “Biodegradation of nonylphenol in river sediment,” Environmental Pollution, vol. 127, no. 127, pp. 425–430, 2004. DOI: 10.18280/ijht.330428.

[9] Jian L, Qiang J, He Y, et al, “Biodegradation of nonylphenol polyethoxylates by denitrifying activated sludge,” Water Research, vol. 42, no. 4-5, pp. 1075–82, 2008. DOI: 10.1016/j.watres.2007.09.031.

[10] Parte S, Rokade K, Mali G, et al, “Biodegradation of sulfonated aromatic amine by Pseudomonas desmolyticum NCIM 2112,” Journal of Chemical & Pharmaceutical Research, vol. 5, no. 4, pp. 335–339, 2013. DOI: 10.1016/j.biortech.2006.05.023.

[11] Rebecca J, “Biodegradation of domestic effluent using different solvent extracts of Murraya koenigii,” Journal of Chemical & Pharmaceutical Research, vol. 5, no. 2, pp. 279–282, 2008. DOI: 10.18280/ijht.330428.

[12] Y.L. Huang, W. Wei, J. F.Su, et al, “Experimental study on nitrogen removal of micro polluted source water by the via in situ biological contact oxidation,” Water Treatment Technology, vol. 36, no. 6, pp. 95–99, 2010. 

[13] Okayasu Y, Komori K, Suzuki Y, Tanaka H, Yasojima M, “Nonylphenol formation from nonylphenol ethoxylates in activated sludge process,” Journal of Japan Society on Water Environment, vol. 28, no. 11, pp. 671–676, 2005. DOI: 10.2965/jswe.28.671.

[14] R. Jiang, Z.B. Yu, J. Li, et al, “Current situation analysis of biological contact oxidation process,” Environmental Science and Management, vol. 38, no. 5, pp. 61–63, 2013. 

[15] Eaton A. D, Clesceri L S, Greenberg A E, “Standard methods for the examination of water and wastewater (19th ed),” Washington DC: APHA, vol. 399, no. 1-3, pp. 121–127, 008. 

[16] Kanda J, “Determination of ammonium in seawater based on the indophenol reaction with O-phenylphenol (OPP),” Water Res., vol. 29, no. 12, pp. 2746–2750, 1995.